Windows 2012+ Solution:
Method #1
Add-WindowsFeature Web-WMI | Format-List Get-CimInstance -Namespace root/MicrosoftIISv2 -ClassName IIsApplicationPoolSetting -Property Name, WAMUserName, WAMUserPass | select Name, WAMUserName, WAMUserPass
Method #2
(Get-Item website).ProcessModel (Get-Item website).ProcessModel.username (Get-Item website).ProcessModel.password
Windows 2008/R2 Solution
cd C:\Windows\system32\inetsrv .\appcmd.exe list apppool /text:*
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